Why is CO2 a gas while SiO2 is a solid at room temperature?
Answer:
C can form multiple bonds with O as the orbitals used of the lateral overlap are of same size and energy, thus satisfying its valancies by forming 2 s bonds and 2 p bonds with O. Si cannot form such multiple bonds with O as the orbitals overlapping laterally will be of different size and energy. So, Si satisfies all its valancies by forming 4 s bonds with O. This results in CO2 being monomeric and SiO2 being polymeric and hence CO2 is a gas and SiO2 is a solid at room temperature.
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