Saturday, October 15, 2011

Question on Cell emf

The Standard Reduction Potentials of Pb2+/Pb and Cu2+/Cu couples are -0.76V and +0.34V respectively. What will be the standard emf of the cell constructed with the two couples mentioned above?


Answer:


From the SRPs given in the question it could be found that, for the cell to be spontaneous Pb2+/Pb should act as the anode and Cu2+/Cu should act as the cathode. Also,


EoCell = EoCathode - EoAnode = 0.34 - (-0.76) = 0.34 + 0.76 = 1.1V

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