Tuesday, August 30, 2011

Question on Disproportionation

Which one among HClO, HClO2, HClO3 and HClO4 does not undergo disproportionation?


Answer:


Disproportionation is the process in which an element undergoes both oxidation and reduction in a reaction. Moreover, an element can show a maximum oxidation state equal to its “group number” and a minimum oxidation state equal to its “group number – 8”. Among the oxyacids of chlorine given, in HClO4 chlorine is in its highest oxidation state (+7). So, it cannot undergo further oxidation and hence HClO4 cannot undergo dispropotionation.

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